Eglo Unfortunately, there is no convenient way to simplify a workflow that requires switching back and forth between After Effects and Spine. The only thing I can suggest is that the PNG export can be done from the CLI, and when you run it from the CLI, another instance is run to do the export, so you can still work in Spine while waiting for the export.
We have provided a script that makes it easy to do exports from the CLI, so if you are interested, see the following blog post for more information: Blog - New export shell scripts